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Grading Xerneas #64 from Mega Evolution isn't worth it at current prices. At $0.16 raw against $25.00 for a PSA 10, that works out to -72% ROG. Grading and shipping fees would eat whatever margin is there.
Among the 71 cards in Mega Evolution with PSA 10 sale data, Xerneas ranks 63rd for Return on Grading and 65th by PSA 10 price. Of the 3 Rare cards with PSA 10 sales, it is 2nd for Return on Grading. The median PSA 10 in this set sells for $44.99. 3 of the 71 clear a 100% Return on Grading.
