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Sending the Rare Froslass from Twilight Masquerade to PSA would most likely lose money today. Raw copies trade around $0.30 while PSA 10s sell for about $49.00, a -46% Return on Grading. Grading and shipping fees would eat whatever margin is there.
Among the 92 cards in Twilight Masquerade with PSA 10 sale data, Froslass ranks 50th for Return on Grading and 52nd by PSA 10 price. Of the 8 Rare cards with PSA 10 sales, it is 5th for Return on Grading. The median PSA 10 in this set sells for $57.14. 4 of the 92 clear a 100% Return on Grading.
