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Sending Marshadow #80 from Evolving Skies to PSA would most likely lose money today. At $0.27 raw against $49.98 for a PSA 10, that works out to -45% ROG. Grading and shipping fees would eat whatever margin is there.
Among the 122 cards in Evolving Skies with PSA 10 sale data, Marshadow ranks 82nd for Return on Grading and 86th by PSA 10 price. Of the 14 Rare Holo cards with PSA 10 sales, it is 5th for Return on Grading. The median PSA 10 in this set sells for $78.59. 7 of the 122 clear a 100% Return on Grading.
